Measurements of Mass and Surface Exhalation Rate from Soil of

Transcript Of Measurements of Mass and Surface Exhalation Rate from Soil of
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
Measurements of Mass and Surface Exhalation Rate from Soil of Eastern Haryana, India
Amanjeet1*, Ajay Kumar2 and Suneel Kumar1 1Department of Physics, Chandigarh University, Gharuan, Mohali, Punjab, 140413 India.
2Post Graduate Department of Physics, DAV College Amritsar, Punjab, 143001 India.
*(Corresponding author: [email protected])
Abstract
Radon is the inert gas which is important for indoor radiation dose. More than half of radiation dose received by human being from radon. Radon is the decay product of radium which depends upon the radioactivity in building materials. Radon exhalation rate from the building material is an important issue. The radon mass exhalation rate and thoron surface exhalation rate have been estimated by means of SMART RnDuo in surface soil samples collected from Eastern Haryana. The radon mass exhalation rate and thoron surface exhalation rate are varied from 9.8 to 34.1 mBq/kg/h and 170.5 to 542.8 mBq/m2/s with average value 19.01 mBq/kg/h and 370.38 mBq/m2/s, respectively.
Keywords: Radon Mass exhalation rate, Thoron Surface exhalation rate, Radium, Radioactivity
INTRODUCTION:
Natural radiations originate in the environment from the natural as well as manmade sources. Sources include cosmic radiation naturally occurring radioactive material such as radon, thoron and fallout from nuclear weapons testing and nuclear accident. The biggest source of natural background radiation is airborne radon. Indoor air quality is an important issue nowdays because an individual spend more than 80% of their time in houses (BEIR, 1999). Because of ignorance about it, this turns into a potential hazard for living things. In 1956 a term "Radiation Ecology" appeared to indicate this range of the wide field of nature worried with the evaluation of radioactivity in the earth. The improvement and consequent development of atomic vitality for military and quiet purposes has been joined by ecological issues (Mehta et al. 2014).
Soil is the prime source of natural radionuclides such as uranium, thorium and potassium which is used as the building material. Radon is a radioactive inert gas and is the heaviest of the inert gases with atomic number 86 and relative atomic mass 222. There exist quite a few other isotopes of radon besides 222Rn; the most notable one are 220Rn that is known as thoron and 219Rn, which is known as actinon.222Rn and 220Rn are generated from the radioactive decay of radium isotopes, which in turn is a daughter product of natural decay of 238U and 232Th present in the earth’s crust. Actinon is part of decay series of 235U and has such a short half-life (4s) that is
neglected in geochemical exploration. Uranium, thorium and radium are wide spread in the earth’s environment and it exists in various geological formations in soil, rocks, plants, water and air.
Radon is inert gas which is colorless and odorless and is the decay product of radium which lies in the decay series of uranium. Radon is exhaled from the building materials and then inhaled by the residents. The radon exhalation rate depends upon the concentration of radium in soil and other building materials. Radon seeps out of the rocks and soil into the atmosphere (Akerblom et al., 1984) or into ground water or infiltrates into buildings. The rate of radon emanation depend on many factors, such as temperature, moisture content, activity concentration of radionuclide (238U and 226Ra) in soil and rock (Mayya et al., 1998) . Radon and thoron exposure can be enhanced or diminished by human activity, notably house construction. It may raise the concentration of airborne indoor radioactivity to unacceptable levels, especially in places having low ventilation rates places (Verma et al., 2014, Mehta et al., 2015). Basement sealing and suction ventilation reduce radon exposure. Some building materials like soil, rocks may emanate radon if they contain radium and are porous to gas (UNSCEAR, 2006). The indoor concentration of 222Rn and 220Rn depends on the crustal abundance of their parent elements and on their access to building interiors. Thus, types of soil and rocks around the abodes are the main source of 222Rn and 220Rn to which general population is exposed (UNSCEAR, 2000). The radon exhalated from the soil accumulate in indoor environment and adds to 55% inhalation dose According to BEIR reports (BEIR, 1999), the exposure of population to high activity of radon and its progeny a long stretch prompt to neurotic impacts like the respiratory practical changes and the event of lung cancer (ATDSR, 1999). Therefore, it is imperative to concentrate the radon discharge from the building materials.
Many researchers have been studied the radon and thoron in dwellings (Bajwa et al., 2008; Kant et al., 2009; Abu-Haija et al.; 2010; Mehra et al., 2011; Hussein et al., 2013; Singh et al., 2015) and exhalation rate in soil samples (exhalation rate in soil (Turham et al. 2008, Akhtar et al.2005, Shoeib et al.2014, Duggal et al. 2013, Mehta et al., 2015) in the world but Eastern Haryana, Northern India has not been studied for environmental radon and thoron so far. This study focused on radon mass exhalation rate and thoron surface exhalation rate
2181
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
from soil samples of Eastern Haryana in North India.
GEOLOGY OF STUDY AREA Study area is located in Haryana state of India between 28° 40’ 30” to 29° 05’35” north latitude and 76°13’ 22” to 76° 51’ 20” east latitude. The altitude of district is about 220 meter from mean sea level. There is a gentle slope from north to south i.e.19 cm per km upto Jhajjar town in the northern part of the rohtak and there is considerable slope west to east. Jawahar Lal Nehru feeder and Bhalaut sub Branch are main canals. The study area is occupied by IndoGangetic alluvium. There is no surface features worth to mention. Physiographically the area is flat terrain. The area slopes towards northeast to southwest with an average gradient of 0.19 m/km. The soils of the district are fine to medium textured. It comprises sandy loam in Rohtak, Sampla, and Lakhan Majra blocks whereas it is loamy sand with occasional clay loam in Kalanaur and Meham Blocks. The soils of the district are classified as arid brown (Solemnized) and sierozem.
Figure 1: Geology of studied area.
MATERIALS AND METHODS Mass Exhalation Rate The emission of radon per unit area per unit time is called radon mass exhalation rate (Jm). Exhalation rate in soil sample can be measured using SMART RnDuo monitor that is consisting with closed accumulation chamber, which is a stainless steel cylinder with an inner height of 8 cm and radius 4.5 cm with a provision to attach a detector from upper side. SMART RnDuo monitoring the build up of radon concentration in the chamber at regular time intervals of one hour. The basic principle is based on detection of α particles, emitted from sampled radon and its decay progeny formed
inside the detector volume by scintillation with ZnS(Ag). The chamber is the minimum residual volume in a chamber is maintained for accurate exhalation rate measurements. The instrument has a very good sensitivity and low detector volume which is good for sample analysis. In radon measurement mode, the thoron entry at the detector inlet is cut-off by diffusive sampling through pin hole. The alpha scintillations from radon and its decay products formed inside the cell are continuously counted for a user-programmable counting interval by the PMT and the associated counting electronics. The alpha counts obtained are processed by a microprocessor unit as per the developed algorithm to display the concentration of radon (Sahoo et al. 2011). The response time of SMART RnDuo is about 20 min for 63% of chamber radon concentration and 40 min for 95% of chamber radon concentration. Then by least square fitting method the buildup radon oncentration C(t) in Bq/m3 at time t is assessed inside the chamber and radon mass exhalation rate Jm is then obtained by a given equation (Sahoo et al. 2007):
(1)
where Jm represents the radon mass exhalation rate in (Bq/kg/h), M is the mass (kg) of soil sample, V is the effective air volume (m3) of the chamber including the volume of the scintillation cell, λe represents the effective decay constant which is sum of 222Rn decay constant and any chamber leakage rate if exists and C0 is the initial radon concentration in chamber at t=0..
Surface Exhalation Rate
In case of thoron (220Rn) monitoring by scintillation based thoron monitor, program based sampling is carried out using a flow mode sampler connected to the pump inlet of the monitor. In a 15 min cycle, sampling pump is kept ON for initial 5 minutes which gives a measure of thoron and background, followed by a delay of 5 minutes which ensures near complete decay of thoron and then, last 5 minutes counting gives the measure of background counts for that cycle.
The 220Rn surface exhalation rate (Jst) (Bq/m2/s) in soil samples can be obtained from equilibrium concentration of thoron (CT) (Bq/m3) inside the chamber using following equation (Kanse et al.2013;Sahoo et al. 2014):
Jst=CT Vλ/A
(2)
where V is the residual air volume (m3) enclosed by the loop, λ is 220Rn decay constant (0.012464 s-1) and A is the surface area (m2) of sample.
RESULTS AND DISCUSSION
Mass exhalation rate and surface exhalation rate in soil samples of Eastern Haryana, Northern India had been measured using SMART RnDuo monitor. The mass
2182
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
exhalation rate and surface exhalation rate in study area varies from 9.8 to 34.1 mBq/kg/h and 170.5 to 542.8 mBq/m2/s with average value 19.5 mBq/kg/h and 368.1 mBq/m2/s, respectively (Table 1). Mass exhalation rate is maximum in village Sudana with value 34.1 mBq/kg/h and minimum in village of Basana with value of 9.8 mBq/kg/h which is shown in fig 2 . Surface exhalation rate is highest in village of Chandi with value of 542.8 mBq/m2/s and lowest in the village of Basana with the value of 170.5 mBq/m2/s which is shown in fig 3. Mass exhalation rate is high in Sudana village which may be due to high concentration of indoor radon and surface exhalation rate in Chandi village which may be due to high concentration of indoor thoron. Indoor radon and indoor thoron concentration depends upon the activity of uranium and thorium in the building material and water. Uranium and thorium concentration in Eastern Haryana has been reported by Amanjeet et al. 2017. Uranium and thorium concentration in this region is within the safe limits and some village uranium and thorium concentration is high. This region is famous for agriculture and Yamuna river water is main source of irrigation. Yamuna is originating from Aravali Hill which brought down the soil from this hill which the main region
radioactivity in this region. Concentration of uranium and radon in drinking water in Eastern Haryana has been reported by Panghal et al. 2017. Tosham region which is the known area of high radioactivity and indoor radon is the main reason of high exhalation rate in study region. High indoor radon and thoron concentration in Tosham region has been reported by Bajwa et al. 2009. In the study region, granite of Tosham hill is used as a building material for the construction of abodes. Granite shows the high concentration of thorium due to which surface exhalation rate may be high in dwellings of the study region.
Mass exhalation rate in the present study is comparable to Western Haryana reported by Mann et al. 2014 and higher than Ambala (Mehta et al. 2016) and Kuruskhtera (Chauhan et al.2002) while Mohali (Mehta et al. 2015), Kapurthala (Kumar and Kaur, 2014) and Malwa region (Mehra et al.2006) of Punjab have lower value of mass exhalation rate than Central Haryana while Himachal Pradesh (Singh et al.2017) and Uttar Pradesh (Zubair et al.2012) have comparable value of radon mass exhalation rates.
Table 1: Activity concentrations of radon mass exhalation rate and thoron surface exhalation rate in soil samples of Eastern Haryana, India.
Villages
Basana Lahli Nigana Pilana Sundana Chandi Indergarh Lakahan Majra Bedwa Ajab
Locations Code
RH-1 RH-2 RH-3 RH-4 RH-5 RH-6 RH-7 RH-8 RH-9 RH-10 Min Max Average value
Radon mass exhalation rate (mBq/kg/h)
9.8 21.6 14.4 11.3 34.1 28.3 15.3 13.6 26.9 15.3 9.8 34.1 19.01
Thoron surface exhalation rate
(mBq/m2/s) 170.5 537.2
360.8
435.3 529.2 542.8
456.3
195.2 292.7 183.8 170.5 542.8 370.38
CONCLUSION
The mass exhalation rate and surface exhalation rate in study area varies from 9.8 to 34.1 mBq/kg/h and 170.5 to 542.8 mBq/m2/s with average value 19.01 mBq/kg/h and
370.38 mBq/m2/s, respectively. The results in this study show that radiological risk due to natural radiations can be reduced by choices of appropriate building material.
2183
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
Table 2: Comparison of radon mass exhalation rate and thoron surface exhalation rate in other region of India.
Sample Name
Location
Mass exhalation rate (mBq/kg/h)
Surface exhalation rate (mBq/m2/h)
Reference
Soil
Eastern Haryana
19.01
Soil
Amritsar, Punjab
2.23
Soil
Sangrur, Punjab
20.58
Soil
Faridkot, Punjab
19.90
370.38 mBq/m2/s 74.4 724.9 702.0
Present Study Singh et al., 2008 Mehra et al., 2006 Mehra et al., 2006
Soil
Patiala, Punjab
14.78
Soil
Mansa, Punjab
18.50
Soil
Ludhiana, Punjab
12.84
Soil
Moga, Punjab
10.98
Soil
Bathinda, Punjab
14.54
Soil
Mohali, Punjab
1.36
Soil
Malwa region, Punjab 6.4 -36.3
Soil
Pathankot
Punjab
1.91 to 6.55
Soil
Kapurthala Punjab
2.96 to 5.74
520.4 652.0 451.8 386.4 500.69 28.3 224-1278 -
-
soil
Ropar dIstrict, Punjab 7.04
Soil
Tosham Ring, Haryana 7.69
Soil
Kurukshetra, Haryana 5.60
248.19 255.9 154.2
Soil
Ambala, Haryana
7.40
203.6
Soil
Ambala
1.76
39.92
Soil
Sirsa
11.44 to 42.66
210.48-785.03
soil
Yamuna
nagar, 73
Haryana
1683
soil
Panchkula, Haryana
83
1892
soil
Morni Hill, Haryana
12.66
446.63
soil
Kala Amb, Haryana
7.61
268.54
Soil
Delhi
1.13
12.4
Soil
Uttar prdesh
23.1
Soil
Jawalmukhi Thrust, .02417E-04
to
Himachal Pradesh
7.24148E-05
Soil
Hamirpur Mineralaized 22.51 ± 2.2
Zone
Himachal
Pradesh
Soil
Godda, Jharkhand
17.2-22.8
525.4-708.2
rock
Jamtara, Jharkhand
18.3-23.4
543.4-756.4
soil
Chandigarh
6.15
216.87
Mehra et al., 2006 Mehra et al., 2006 Mehra et al., 2006 Mehra et al., 2006 Singh et al., 2005 Mehta et al., 2015 Mehra et al., 2006 Kumar et al., 2014
Kumar and Kaur et al., 2014
Singh et al., 2009
Singh et al., 2008
Chauhan
and
Chakarvarti, 2002
Chauhan
and
Chakarvarti, 2002
Mehta and Shikha, 2016
Mann et al., 2014
Pundir et al. 2014
Pundir et al. 2014 Singh joga 2009 Singh joga 2009 Sonkawade et al. (2008) Zubair et al.2012 Thakur et al., 2015
Singh et al., 2016
Singh et al.2010 Singh et al. 2010 Singh et al. 2009
2184
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
Figure 2: Variation of mass exhalation rate in Eastern Haryana.
REFERENCES
[1] Abu-Haija, O., Salameh, B., Ajlouni, A.W., Abdelsalam, M. and Al-Ebaisat, H. (2010) ‘Measurement of radon concentration inside houses in Tafila Province, Jordan’, International Journal of the Physical Sciences, Vol. 5, No. 6, pp.696-699.
[2] Agency for Toxic Substances and Disease Registry (ATDSR), Report TP-90-29. Atlanta, USA, 1999.
[3] Akerblom, G., Andersson, P. and Clavensjo, B. (1984) ‘Soil Gas Radon: A Source for Indoor Radon Daughters’, Radiation Protection Dosimetry, Vol. 7, pp.49–54.
[4] Akhtar, N., Tufail, M., Ashraf, M. and Iqbal, M. (2005) ‘Measurement of environmental radioactivity for estimation of radiation exposure from saline soil of Lahore, Pakistan’, Radiation Measurements, Vol. 39, pp.11-14.
[5] BEIR VI, Report of the Committee on the Biological effects of Ionizing Radiation, Natl. Res. Council, Natl. Acad. Press, Washington, DC, 1999.
[6] Chauhan R.P. and Chakarvarti, S.K. 2002, Radon exhalation rates from soils and stones as building materials, Indian Journal of Pure and Applied Physics, 40, 670-673
[7] Chauhan R.P., Radon exhalation rates from stone and soil samples of Aravali hills in India Iran. J. Radiat. Res., 2011, 9(1), pp. 57-61.
[8] Duggal, V., Rani, A., Mehra, R., Ramola, R.C., (2013). Assessment of Natural Radioactivity levels and associated dose rates in soil samples from Northern Rajasthan, India’, Radiation Protection Dosimetry, Vol. 158, pp.235-240.
[9] Hussein, Z.A., Jaafar, M.S. and Ismail, A.H. (2013) ‘Measurement of indoor Radon-222 Concentration inside Iraqi Kurdistan: Case Study in the Summer Season’, Journal of Nuclear Medicine and
Figure 3: Variation of surface exhalation rate in Eastern Haryana.
Radiation Therapy, Vol. 4, pp.143.
[10] Kanse, S.D., Sahoo, B.K., Spara, B.K., Gaware, J.J. & Mayya, Y.S., 2013. Powder sandwich technique: A novel method for determining the thoron emanation potential of powders bearing high 224Ra content. Radiation Measurements, 48(1), pp.82–87. doi.org/10.1016/j.radmeas.2012.10.014.
[11] Kant, K., Rashmi, Sonkawade, R.G., Sharma, G.S. and Chauhan, R.P. (2009) ‘Seasonal variation of radon, thoron and their progeny levels in dwellings of Haryana and Western Uttar Pradesh’, Iranian Journal of Radiation Research, Vol. 7, No. 2, pp.79-84.
[12] Kumar A., and A. Kaur, A study of radon concentration in water and radon exhalation rate in soil samples belonging to Kapurthala district, Punjab, India Advances in Applied Science Research, 2014, 5(1), pp.43-47.
[13] Kumar,A., and S.Narang, Estimation of Radon Exhalation Rate and Radium Content in Soil Samples of Pathankot District, Punjab Using LR115 Plastic Detector IJEAR, 2014, Vol. 4, Issue 2, pp. 23-25, ISSN : 2348-0033
[14] Mann, N., S. Kumar, A. Kumar, R.P. Chauhan, A.K. Garg, Measurement of Radon Exhalation Rates in Soil Samples from Western Haryana, ISST Journal of Applied Physics, 2014, Vol. 5 No. 2, pp. 56-59
[15] Mayya, Y.S., Eappen, K.P. and Nambi, K.S.V (1998) ‘Methodology for mixed field inhalation dosimetry in monazite areas using a twin-cup dosemeter with three track detectors’, Radiation Protection Dosimetry, Vol. 77, No.3, pp.177-184.
[16] Mehra, R., S. Singh, K. Singh , A Study of Uranium, Radium, Radon Exhalation Rate and Indoor Radon in the Environs of Some Areas of the
2185
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
Malwa Region, Punjab, Indoor and Built Environment, October 2006, 15 (5), pp. 499-505.
[17] Mehra, R., Badhan, K., Kansal, S. and Sonkawade, R.G. (2011) ‘Assessment of seasonal indoor radon concentration in dwellings of Western Haryana’, Radiation Measurements, Vol. 46, pp.1803-1806.
[18] Mehta, V., D.Shikha, Measurement of Radon Exhalation Rates from Soil Samples of Some Villages of Ambala, Haryana, Sch. J. Phys. Math. Stat., 2016; Vol-3; Issue-2 (Mar-May); pp-66-68.
[19] Mehta, V., R. P. Chauhan, G. S. Mudahar, Radon Exhalation Rates from Some Soil Samples of Nangal, Punjab, IJITKM Special Issue (ICFTEM2014), May 2014 pp. 225-227 (ISSN 0973-4414).
[20] Mehta, V., Singh, S.P., Chauhan, R.P. and Mudahar, G.S. (2015) ‘Study of indoor Radon, Thoron, their Progeny Conectration and Radon Exhalation Rate in the Environs of Mohali, Punjab, Northern India’, Aerosol Air Quality Research, Vol. 15, pp.1380-1389.
[21] Pundir A., Singh R., Kamboj S, Measurement of Radon Concentration and Exhalation Rates in Soil Samples of some districts of Haryana and Himachal in India, Researcher 2014;6(6),71-76
[22] Sahoo, B.K., Agarwal, T.K., Gaware, J.J. & Sapra, B.K., 2014. Thoron interference in radon exhalation rate measured by solid state nuclear track detector based can technique. Journal of Radioanalytical and Nuclear Chemistry, 302(3), pp.1417–1420.
[23] Sahoo, B.K., Nathwani, D, Eappen, K.P., Ramchandarn, T.V., Gaware, J.J. & Mayya, Y.S., 2007. Estimation of radon emanation factor in Indian building materials. Radiation Measurements, 42(8), pp.1422–1425.
[24] Sahoo, B.K., Sapra, B.K., Gaware, J.J., Kanse, S.D. & Mayya, Y.S., 2011. A model to predict radon exhalation from walls to indoor air based on the exhalation from building material samples. Science of the Total Environment, 409(13), pp.2635–2641
[25] Shoeib, M.Y. and Thabayneh, K.M. (2014) ‘Assessment of natural radiation exposure and radon exhalation rate in various samples of Egyptian building materials’, Journal of Radiation Research and Applied Sciences, Vol. 7,No.2, pp.174-181.
[26] Singh B P, Pandit B, Bhardwaj V N, Singh Paramjit, Kumar Rajesh, Study of radium and radon exhalation in some solid samples using solid state nuclear track detectors,Indian Journal of Pure and Applied physics, 48, 493-495, 2010
[27] Singh J., Singh H., SINGH S., Bajwa B.S., Uranium, radium and radon exhalation studies in some soil samples using plastic track detectors, Indian of physics, 83(8), 1147-1153, 2009
[28] Singh, P., Singh, P., Singh, S., Sahoo, B.K., Sapra, B.K. and Bajwa, B.S. (2015) ‘A study of indoor radon, thoron and their progeny measurement in Tosham region Haryana, India’, Journal of Radiation Research Applied Sciences, Vol. 8, No. 2, 226-233.
[29] Thakur, N., J. Kumar, B. Thakur, R.Bhadwal, K. C. Thakur and Y. Sharma, Radioactivity Measurements along Jwalamukhi Thrust in Himachal Pradesh, India CPUH-Research Journal: 2015, 1(2), pp. 23-27 ISSN (Online): 2455-6076
[30] Turham, S., Baykan, U. N. and Sen, K. (2008) ‘Measurement of the natural radioactivity in building materials used in Ankara and assessment of external doses’, Journal of Radiological Protection, Vol. 28, pp.83-91.
[31] UNSCEAR (United Nation Scientific Committee on the Effects of Atomic Radiation) (2000) Sources and Effects of Ionizing Radiation, United Nations: New York, United Nation.
[32] UNSCEAR (United Nation Scientific Committee on the Effects of Atomic Radiation) (2006) Sources and Effects of Ionizing Radiation, United Nations: New York, United Nation
[33] Verma, D. and Khan, M.S. (2014) ‘Assessment of Indoor Radon, Thoron and Their Progeny in Dwellings of Bareilly City of Northern India Using Track Etch Detectors’, Romanian Journal of Physics, Vol. 59, No.1–2, pp.172–182.
[34] Zubair,M., M. Shakir Khan, D. Verma Measurement of radium concentration and radon exhalation rates of soil samplescollected from some areas of Bulandshahr district, Uttar Pradesh, India using plastic track detectors Iran. J. Radiat. Res., 2012, 10(2), pp. 83-87
2186
Measurements of Mass and Surface Exhalation Rate from Soil of Eastern Haryana, India
Amanjeet1*, Ajay Kumar2 and Suneel Kumar1 1Department of Physics, Chandigarh University, Gharuan, Mohali, Punjab, 140413 India.
2Post Graduate Department of Physics, DAV College Amritsar, Punjab, 143001 India.
*(Corresponding author: [email protected])
Abstract
Radon is the inert gas which is important for indoor radiation dose. More than half of radiation dose received by human being from radon. Radon is the decay product of radium which depends upon the radioactivity in building materials. Radon exhalation rate from the building material is an important issue. The radon mass exhalation rate and thoron surface exhalation rate have been estimated by means of SMART RnDuo in surface soil samples collected from Eastern Haryana. The radon mass exhalation rate and thoron surface exhalation rate are varied from 9.8 to 34.1 mBq/kg/h and 170.5 to 542.8 mBq/m2/s with average value 19.01 mBq/kg/h and 370.38 mBq/m2/s, respectively.
Keywords: Radon Mass exhalation rate, Thoron Surface exhalation rate, Radium, Radioactivity
INTRODUCTION:
Natural radiations originate in the environment from the natural as well as manmade sources. Sources include cosmic radiation naturally occurring radioactive material such as radon, thoron and fallout from nuclear weapons testing and nuclear accident. The biggest source of natural background radiation is airborne radon. Indoor air quality is an important issue nowdays because an individual spend more than 80% of their time in houses (BEIR, 1999). Because of ignorance about it, this turns into a potential hazard for living things. In 1956 a term "Radiation Ecology" appeared to indicate this range of the wide field of nature worried with the evaluation of radioactivity in the earth. The improvement and consequent development of atomic vitality for military and quiet purposes has been joined by ecological issues (Mehta et al. 2014).
Soil is the prime source of natural radionuclides such as uranium, thorium and potassium which is used as the building material. Radon is a radioactive inert gas and is the heaviest of the inert gases with atomic number 86 and relative atomic mass 222. There exist quite a few other isotopes of radon besides 222Rn; the most notable one are 220Rn that is known as thoron and 219Rn, which is known as actinon.222Rn and 220Rn are generated from the radioactive decay of radium isotopes, which in turn is a daughter product of natural decay of 238U and 232Th present in the earth’s crust. Actinon is part of decay series of 235U and has such a short half-life (4s) that is
neglected in geochemical exploration. Uranium, thorium and radium are wide spread in the earth’s environment and it exists in various geological formations in soil, rocks, plants, water and air.
Radon is inert gas which is colorless and odorless and is the decay product of radium which lies in the decay series of uranium. Radon is exhaled from the building materials and then inhaled by the residents. The radon exhalation rate depends upon the concentration of radium in soil and other building materials. Radon seeps out of the rocks and soil into the atmosphere (Akerblom et al., 1984) or into ground water or infiltrates into buildings. The rate of radon emanation depend on many factors, such as temperature, moisture content, activity concentration of radionuclide (238U and 226Ra) in soil and rock (Mayya et al., 1998) . Radon and thoron exposure can be enhanced or diminished by human activity, notably house construction. It may raise the concentration of airborne indoor radioactivity to unacceptable levels, especially in places having low ventilation rates places (Verma et al., 2014, Mehta et al., 2015). Basement sealing and suction ventilation reduce radon exposure. Some building materials like soil, rocks may emanate radon if they contain radium and are porous to gas (UNSCEAR, 2006). The indoor concentration of 222Rn and 220Rn depends on the crustal abundance of their parent elements and on their access to building interiors. Thus, types of soil and rocks around the abodes are the main source of 222Rn and 220Rn to which general population is exposed (UNSCEAR, 2000). The radon exhalated from the soil accumulate in indoor environment and adds to 55% inhalation dose According to BEIR reports (BEIR, 1999), the exposure of population to high activity of radon and its progeny a long stretch prompt to neurotic impacts like the respiratory practical changes and the event of lung cancer (ATDSR, 1999). Therefore, it is imperative to concentrate the radon discharge from the building materials.
Many researchers have been studied the radon and thoron in dwellings (Bajwa et al., 2008; Kant et al., 2009; Abu-Haija et al.; 2010; Mehra et al., 2011; Hussein et al., 2013; Singh et al., 2015) and exhalation rate in soil samples (exhalation rate in soil (Turham et al. 2008, Akhtar et al.2005, Shoeib et al.2014, Duggal et al. 2013, Mehta et al., 2015) in the world but Eastern Haryana, Northern India has not been studied for environmental radon and thoron so far. This study focused on radon mass exhalation rate and thoron surface exhalation rate
2181
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
from soil samples of Eastern Haryana in North India.
GEOLOGY OF STUDY AREA Study area is located in Haryana state of India between 28° 40’ 30” to 29° 05’35” north latitude and 76°13’ 22” to 76° 51’ 20” east latitude. The altitude of district is about 220 meter from mean sea level. There is a gentle slope from north to south i.e.19 cm per km upto Jhajjar town in the northern part of the rohtak and there is considerable slope west to east. Jawahar Lal Nehru feeder and Bhalaut sub Branch are main canals. The study area is occupied by IndoGangetic alluvium. There is no surface features worth to mention. Physiographically the area is flat terrain. The area slopes towards northeast to southwest with an average gradient of 0.19 m/km. The soils of the district are fine to medium textured. It comprises sandy loam in Rohtak, Sampla, and Lakhan Majra blocks whereas it is loamy sand with occasional clay loam in Kalanaur and Meham Blocks. The soils of the district are classified as arid brown (Solemnized) and sierozem.
Figure 1: Geology of studied area.
MATERIALS AND METHODS Mass Exhalation Rate The emission of radon per unit area per unit time is called radon mass exhalation rate (Jm). Exhalation rate in soil sample can be measured using SMART RnDuo monitor that is consisting with closed accumulation chamber, which is a stainless steel cylinder with an inner height of 8 cm and radius 4.5 cm with a provision to attach a detector from upper side. SMART RnDuo monitoring the build up of radon concentration in the chamber at regular time intervals of one hour. The basic principle is based on detection of α particles, emitted from sampled radon and its decay progeny formed
inside the detector volume by scintillation with ZnS(Ag). The chamber is the minimum residual volume in a chamber is maintained for accurate exhalation rate measurements. The instrument has a very good sensitivity and low detector volume which is good for sample analysis. In radon measurement mode, the thoron entry at the detector inlet is cut-off by diffusive sampling through pin hole. The alpha scintillations from radon and its decay products formed inside the cell are continuously counted for a user-programmable counting interval by the PMT and the associated counting electronics. The alpha counts obtained are processed by a microprocessor unit as per the developed algorithm to display the concentration of radon (Sahoo et al. 2011). The response time of SMART RnDuo is about 20 min for 63% of chamber radon concentration and 40 min for 95% of chamber radon concentration. Then by least square fitting method the buildup radon oncentration C(t) in Bq/m3 at time t is assessed inside the chamber and radon mass exhalation rate Jm is then obtained by a given equation (Sahoo et al. 2007):
(1)
where Jm represents the radon mass exhalation rate in (Bq/kg/h), M is the mass (kg) of soil sample, V is the effective air volume (m3) of the chamber including the volume of the scintillation cell, λe represents the effective decay constant which is sum of 222Rn decay constant and any chamber leakage rate if exists and C0 is the initial radon concentration in chamber at t=0..
Surface Exhalation Rate
In case of thoron (220Rn) monitoring by scintillation based thoron monitor, program based sampling is carried out using a flow mode sampler connected to the pump inlet of the monitor. In a 15 min cycle, sampling pump is kept ON for initial 5 minutes which gives a measure of thoron and background, followed by a delay of 5 minutes which ensures near complete decay of thoron and then, last 5 minutes counting gives the measure of background counts for that cycle.
The 220Rn surface exhalation rate (Jst) (Bq/m2/s) in soil samples can be obtained from equilibrium concentration of thoron (CT) (Bq/m3) inside the chamber using following equation (Kanse et al.2013;Sahoo et al. 2014):
Jst=CT Vλ/A
(2)
where V is the residual air volume (m3) enclosed by the loop, λ is 220Rn decay constant (0.012464 s-1) and A is the surface area (m2) of sample.
RESULTS AND DISCUSSION
Mass exhalation rate and surface exhalation rate in soil samples of Eastern Haryana, Northern India had been measured using SMART RnDuo monitor. The mass
2182
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
exhalation rate and surface exhalation rate in study area varies from 9.8 to 34.1 mBq/kg/h and 170.5 to 542.8 mBq/m2/s with average value 19.5 mBq/kg/h and 368.1 mBq/m2/s, respectively (Table 1). Mass exhalation rate is maximum in village Sudana with value 34.1 mBq/kg/h and minimum in village of Basana with value of 9.8 mBq/kg/h which is shown in fig 2 . Surface exhalation rate is highest in village of Chandi with value of 542.8 mBq/m2/s and lowest in the village of Basana with the value of 170.5 mBq/m2/s which is shown in fig 3. Mass exhalation rate is high in Sudana village which may be due to high concentration of indoor radon and surface exhalation rate in Chandi village which may be due to high concentration of indoor thoron. Indoor radon and indoor thoron concentration depends upon the activity of uranium and thorium in the building material and water. Uranium and thorium concentration in Eastern Haryana has been reported by Amanjeet et al. 2017. Uranium and thorium concentration in this region is within the safe limits and some village uranium and thorium concentration is high. This region is famous for agriculture and Yamuna river water is main source of irrigation. Yamuna is originating from Aravali Hill which brought down the soil from this hill which the main region
radioactivity in this region. Concentration of uranium and radon in drinking water in Eastern Haryana has been reported by Panghal et al. 2017. Tosham region which is the known area of high radioactivity and indoor radon is the main reason of high exhalation rate in study region. High indoor radon and thoron concentration in Tosham region has been reported by Bajwa et al. 2009. In the study region, granite of Tosham hill is used as a building material for the construction of abodes. Granite shows the high concentration of thorium due to which surface exhalation rate may be high in dwellings of the study region.
Mass exhalation rate in the present study is comparable to Western Haryana reported by Mann et al. 2014 and higher than Ambala (Mehta et al. 2016) and Kuruskhtera (Chauhan et al.2002) while Mohali (Mehta et al. 2015), Kapurthala (Kumar and Kaur, 2014) and Malwa region (Mehra et al.2006) of Punjab have lower value of mass exhalation rate than Central Haryana while Himachal Pradesh (Singh et al.2017) and Uttar Pradesh (Zubair et al.2012) have comparable value of radon mass exhalation rates.
Table 1: Activity concentrations of radon mass exhalation rate and thoron surface exhalation rate in soil samples of Eastern Haryana, India.
Villages
Basana Lahli Nigana Pilana Sundana Chandi Indergarh Lakahan Majra Bedwa Ajab
Locations Code
RH-1 RH-2 RH-3 RH-4 RH-5 RH-6 RH-7 RH-8 RH-9 RH-10 Min Max Average value
Radon mass exhalation rate (mBq/kg/h)
9.8 21.6 14.4 11.3 34.1 28.3 15.3 13.6 26.9 15.3 9.8 34.1 19.01
Thoron surface exhalation rate
(mBq/m2/s) 170.5 537.2
360.8
435.3 529.2 542.8
456.3
195.2 292.7 183.8 170.5 542.8 370.38
CONCLUSION
The mass exhalation rate and surface exhalation rate in study area varies from 9.8 to 34.1 mBq/kg/h and 170.5 to 542.8 mBq/m2/s with average value 19.01 mBq/kg/h and
370.38 mBq/m2/s, respectively. The results in this study show that radiological risk due to natural radiations can be reduced by choices of appropriate building material.
2183
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
Table 2: Comparison of radon mass exhalation rate and thoron surface exhalation rate in other region of India.
Sample Name
Location
Mass exhalation rate (mBq/kg/h)
Surface exhalation rate (mBq/m2/h)
Reference
Soil
Eastern Haryana
19.01
Soil
Amritsar, Punjab
2.23
Soil
Sangrur, Punjab
20.58
Soil
Faridkot, Punjab
19.90
370.38 mBq/m2/s 74.4 724.9 702.0
Present Study Singh et al., 2008 Mehra et al., 2006 Mehra et al., 2006
Soil
Patiala, Punjab
14.78
Soil
Mansa, Punjab
18.50
Soil
Ludhiana, Punjab
12.84
Soil
Moga, Punjab
10.98
Soil
Bathinda, Punjab
14.54
Soil
Mohali, Punjab
1.36
Soil
Malwa region, Punjab 6.4 -36.3
Soil
Pathankot
Punjab
1.91 to 6.55
Soil
Kapurthala Punjab
2.96 to 5.74
520.4 652.0 451.8 386.4 500.69 28.3 224-1278 -
-
soil
Ropar dIstrict, Punjab 7.04
Soil
Tosham Ring, Haryana 7.69
Soil
Kurukshetra, Haryana 5.60
248.19 255.9 154.2
Soil
Ambala, Haryana
7.40
203.6
Soil
Ambala
1.76
39.92
Soil
Sirsa
11.44 to 42.66
210.48-785.03
soil
Yamuna
nagar, 73
Haryana
1683
soil
Panchkula, Haryana
83
1892
soil
Morni Hill, Haryana
12.66
446.63
soil
Kala Amb, Haryana
7.61
268.54
Soil
Delhi
1.13
12.4
Soil
Uttar prdesh
23.1
Soil
Jawalmukhi Thrust, .02417E-04
to
Himachal Pradesh
7.24148E-05
Soil
Hamirpur Mineralaized 22.51 ± 2.2
Zone
Himachal
Pradesh
Soil
Godda, Jharkhand
17.2-22.8
525.4-708.2
rock
Jamtara, Jharkhand
18.3-23.4
543.4-756.4
soil
Chandigarh
6.15
216.87
Mehra et al., 2006 Mehra et al., 2006 Mehra et al., 2006 Mehra et al., 2006 Singh et al., 2005 Mehta et al., 2015 Mehra et al., 2006 Kumar et al., 2014
Kumar and Kaur et al., 2014
Singh et al., 2009
Singh et al., 2008
Chauhan
and
Chakarvarti, 2002
Chauhan
and
Chakarvarti, 2002
Mehta and Shikha, 2016
Mann et al., 2014
Pundir et al. 2014
Pundir et al. 2014 Singh joga 2009 Singh joga 2009 Sonkawade et al. (2008) Zubair et al.2012 Thakur et al., 2015
Singh et al., 2016
Singh et al.2010 Singh et al. 2010 Singh et al. 2009
2184
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
Figure 2: Variation of mass exhalation rate in Eastern Haryana.
REFERENCES
[1] Abu-Haija, O., Salameh, B., Ajlouni, A.W., Abdelsalam, M. and Al-Ebaisat, H. (2010) ‘Measurement of radon concentration inside houses in Tafila Province, Jordan’, International Journal of the Physical Sciences, Vol. 5, No. 6, pp.696-699.
[2] Agency for Toxic Substances and Disease Registry (ATDSR), Report TP-90-29. Atlanta, USA, 1999.
[3] Akerblom, G., Andersson, P. and Clavensjo, B. (1984) ‘Soil Gas Radon: A Source for Indoor Radon Daughters’, Radiation Protection Dosimetry, Vol. 7, pp.49–54.
[4] Akhtar, N., Tufail, M., Ashraf, M. and Iqbal, M. (2005) ‘Measurement of environmental radioactivity for estimation of radiation exposure from saline soil of Lahore, Pakistan’, Radiation Measurements, Vol. 39, pp.11-14.
[5] BEIR VI, Report of the Committee on the Biological effects of Ionizing Radiation, Natl. Res. Council, Natl. Acad. Press, Washington, DC, 1999.
[6] Chauhan R.P. and Chakarvarti, S.K. 2002, Radon exhalation rates from soils and stones as building materials, Indian Journal of Pure and Applied Physics, 40, 670-673
[7] Chauhan R.P., Radon exhalation rates from stone and soil samples of Aravali hills in India Iran. J. Radiat. Res., 2011, 9(1), pp. 57-61.
[8] Duggal, V., Rani, A., Mehra, R., Ramola, R.C., (2013). Assessment of Natural Radioactivity levels and associated dose rates in soil samples from Northern Rajasthan, India’, Radiation Protection Dosimetry, Vol. 158, pp.235-240.
[9] Hussein, Z.A., Jaafar, M.S. and Ismail, A.H. (2013) ‘Measurement of indoor Radon-222 Concentration inside Iraqi Kurdistan: Case Study in the Summer Season’, Journal of Nuclear Medicine and
Figure 3: Variation of surface exhalation rate in Eastern Haryana.
Radiation Therapy, Vol. 4, pp.143.
[10] Kanse, S.D., Sahoo, B.K., Spara, B.K., Gaware, J.J. & Mayya, Y.S., 2013. Powder sandwich technique: A novel method for determining the thoron emanation potential of powders bearing high 224Ra content. Radiation Measurements, 48(1), pp.82–87. doi.org/10.1016/j.radmeas.2012.10.014.
[11] Kant, K., Rashmi, Sonkawade, R.G., Sharma, G.S. and Chauhan, R.P. (2009) ‘Seasonal variation of radon, thoron and their progeny levels in dwellings of Haryana and Western Uttar Pradesh’, Iranian Journal of Radiation Research, Vol. 7, No. 2, pp.79-84.
[12] Kumar A., and A. Kaur, A study of radon concentration in water and radon exhalation rate in soil samples belonging to Kapurthala district, Punjab, India Advances in Applied Science Research, 2014, 5(1), pp.43-47.
[13] Kumar,A., and S.Narang, Estimation of Radon Exhalation Rate and Radium Content in Soil Samples of Pathankot District, Punjab Using LR115 Plastic Detector IJEAR, 2014, Vol. 4, Issue 2, pp. 23-25, ISSN : 2348-0033
[14] Mann, N., S. Kumar, A. Kumar, R.P. Chauhan, A.K. Garg, Measurement of Radon Exhalation Rates in Soil Samples from Western Haryana, ISST Journal of Applied Physics, 2014, Vol. 5 No. 2, pp. 56-59
[15] Mayya, Y.S., Eappen, K.P. and Nambi, K.S.V (1998) ‘Methodology for mixed field inhalation dosimetry in monazite areas using a twin-cup dosemeter with three track detectors’, Radiation Protection Dosimetry, Vol. 77, No.3, pp.177-184.
[16] Mehra, R., S. Singh, K. Singh , A Study of Uranium, Radium, Radon Exhalation Rate and Indoor Radon in the Environs of Some Areas of the
2185
International Journal of Applied Engineering Research ISSN 0973-4562 Volume 13, Number 5 (2018) pp. 2181-2186 © Research India Publications. http://www.ripublication.com
Malwa Region, Punjab, Indoor and Built Environment, October 2006, 15 (5), pp. 499-505.
[17] Mehra, R., Badhan, K., Kansal, S. and Sonkawade, R.G. (2011) ‘Assessment of seasonal indoor radon concentration in dwellings of Western Haryana’, Radiation Measurements, Vol. 46, pp.1803-1806.
[18] Mehta, V., D.Shikha, Measurement of Radon Exhalation Rates from Soil Samples of Some Villages of Ambala, Haryana, Sch. J. Phys. Math. Stat., 2016; Vol-3; Issue-2 (Mar-May); pp-66-68.
[19] Mehta, V., R. P. Chauhan, G. S. Mudahar, Radon Exhalation Rates from Some Soil Samples of Nangal, Punjab, IJITKM Special Issue (ICFTEM2014), May 2014 pp. 225-227 (ISSN 0973-4414).
[20] Mehta, V., Singh, S.P., Chauhan, R.P. and Mudahar, G.S. (2015) ‘Study of indoor Radon, Thoron, their Progeny Conectration and Radon Exhalation Rate in the Environs of Mohali, Punjab, Northern India’, Aerosol Air Quality Research, Vol. 15, pp.1380-1389.
[21] Pundir A., Singh R., Kamboj S, Measurement of Radon Concentration and Exhalation Rates in Soil Samples of some districts of Haryana and Himachal in India, Researcher 2014;6(6),71-76
[22] Sahoo, B.K., Agarwal, T.K., Gaware, J.J. & Sapra, B.K., 2014. Thoron interference in radon exhalation rate measured by solid state nuclear track detector based can technique. Journal of Radioanalytical and Nuclear Chemistry, 302(3), pp.1417–1420.
[23] Sahoo, B.K., Nathwani, D, Eappen, K.P., Ramchandarn, T.V., Gaware, J.J. & Mayya, Y.S., 2007. Estimation of radon emanation factor in Indian building materials. Radiation Measurements, 42(8), pp.1422–1425.
[24] Sahoo, B.K., Sapra, B.K., Gaware, J.J., Kanse, S.D. & Mayya, Y.S., 2011. A model to predict radon exhalation from walls to indoor air based on the exhalation from building material samples. Science of the Total Environment, 409(13), pp.2635–2641
[25] Shoeib, M.Y. and Thabayneh, K.M. (2014) ‘Assessment of natural radiation exposure and radon exhalation rate in various samples of Egyptian building materials’, Journal of Radiation Research and Applied Sciences, Vol. 7,No.2, pp.174-181.
[26] Singh B P, Pandit B, Bhardwaj V N, Singh Paramjit, Kumar Rajesh, Study of radium and radon exhalation in some solid samples using solid state nuclear track detectors,Indian Journal of Pure and Applied physics, 48, 493-495, 2010
[27] Singh J., Singh H., SINGH S., Bajwa B.S., Uranium, radium and radon exhalation studies in some soil samples using plastic track detectors, Indian of physics, 83(8), 1147-1153, 2009
[28] Singh, P., Singh, P., Singh, S., Sahoo, B.K., Sapra, B.K. and Bajwa, B.S. (2015) ‘A study of indoor radon, thoron and their progeny measurement in Tosham region Haryana, India’, Journal of Radiation Research Applied Sciences, Vol. 8, No. 2, 226-233.
[29] Thakur, N., J. Kumar, B. Thakur, R.Bhadwal, K. C. Thakur and Y. Sharma, Radioactivity Measurements along Jwalamukhi Thrust in Himachal Pradesh, India CPUH-Research Journal: 2015, 1(2), pp. 23-27 ISSN (Online): 2455-6076
[30] Turham, S., Baykan, U. N. and Sen, K. (2008) ‘Measurement of the natural radioactivity in building materials used in Ankara and assessment of external doses’, Journal of Radiological Protection, Vol. 28, pp.83-91.
[31] UNSCEAR (United Nation Scientific Committee on the Effects of Atomic Radiation) (2000) Sources and Effects of Ionizing Radiation, United Nations: New York, United Nation.
[32] UNSCEAR (United Nation Scientific Committee on the Effects of Atomic Radiation) (2006) Sources and Effects of Ionizing Radiation, United Nations: New York, United Nation
[33] Verma, D. and Khan, M.S. (2014) ‘Assessment of Indoor Radon, Thoron and Their Progeny in Dwellings of Bareilly City of Northern India Using Track Etch Detectors’, Romanian Journal of Physics, Vol. 59, No.1–2, pp.172–182.
[34] Zubair,M., M. Shakir Khan, D. Verma Measurement of radium concentration and radon exhalation rates of soil samplescollected from some areas of Bulandshahr district, Uttar Pradesh, India using plastic track detectors Iran. J. Radiat. Res., 2012, 10(2), pp. 83-87
2186